flexible composite parts in three-dimensional format and method of production of these parts

专利摘要:
SYSTEMS AND METHOD FOR PRODUCTION OF THREE-DIMENSIONAL ARTICLES FROM FLEXIBLE COMPOSITE MATERIALS The present disclosure covers three-dimensional articles comprising flexible composite materials and methods of manufacturing said three-dimensional articles. More particularly, the present system relates to methods for making seamless three-dimensional shaped articles usable for such finished products as inflatable/air bag structures, bags, shoes and similar three-dimensional products. A preferred manufacturing process combines composite molding methods with specific precursor materials to form fiber reinforced continuous shaped articles that are flexible and deformable.
公开号:BR112015010690B1
申请号:R112015010690-0
申请日:2013-11-09
公开日:2021-05-11
发明作者:Roland Joseph Downs；Christopher Michael Adams；Jon Michael Holweger
申请人:Dsm Ip Assets B.V；
IPC主号:

专利说明:

CROSS REFERENCE TO RELATED ORDERS
[01] This application claims priority to the Provisional Patent Application under serial number US61/724,375 filed November 9, 2012; Provisional Patent Application under serial number US61/780,312 filed March 13, 2013; and Provisional Patent Application under serial number US61/800,452 filed March 15, 2013, which are incorporated herein by reference in their entirety. FIELD OF THE INVENTION
[002] The present disclosure relates to a system and a method for producing three-dimensional articles from flexible composite materials. For example, the present disclosure relates to systems and methods for manufacturing three-dimensionally shaped articles for inflatable/air bag structures, bags, shoes and similar three-dimensional articles, based on flexible composite materials. BACKGROUND OF THE INVENTION
[03] In relation to fabric-related products, there is a continuing difficulty in optimizing various combinations of properties such as weight, stiffness, penetrability, water resistance, breathability, color, moldability, cost, ability to personalization, flexibility, packaging capability, and the like, especially with respect to fabric-related products such as apparel and shoes, hiking and camping products, comfortable armor, protective inflatable products, and the like.
[04] For example, current market trends are faced with the expansion of automotive airbag technology in many new applications including aircraft, bus and train/high speed rail systems, and for neck support and personal head in sports, motorcycling, motor sports or military applications. This same technology has applications in emergency systems and other commercial buoyancy systems, emergency buoyancy apparel and appliances, avalanche protection, oil and chemical splash control, water reservoirs for outdoor applications, backpacks, tents and storage systems generally. Trends in air bag technology seek the development of lightweight, thin, high-strength pressure-proof envelopes that are resistant to impact and puncture.
[005] For many sporting activities, the same importance is in the weight and strength of the participant's wearable equipment. This is especially true in sports and athletic shoes where a primary objective is to provide footwear that is as light as possible, yet at the same time retains essential biomechanical structural support properties.
[006] For these reasons at least, the development of new, cost-effective, fabric-related articles with reduced weight and required structural performance, and new systems and methods for manufacturing fabric-related articles, would be of great benefit. SUMMARY OF THE INVENTION
[007] In various aspects of the present disclosure, systems and methods for producing three-dimensional articles from various flexible composite materials are disclosed.
[008] In various aspects of the present disclosure, improved products, methods and equipment related to monofilament are provided, along with systems for producing three-dimensional articles from flexible composite materials.
[009] In various aspects of the present disclosure, systems for the design and manufacture of fabric-related products that use the useful technologies and techniques taught and incorporated in the present invention are described.
[010] In various aspects of the present disclosure, improvements in the efficient control of properties of fabric-related products are disclosed, including, but not limited to: weight, stiffness, penetrability, water resistance, breathability, color , moldability, cost, customizability, flexibility, packageability, etc., including such desired combinations of such properties.
[011] In various aspects of the present disclosure, methods are disclosed for manufacturing articles in three-dimensional format based on flexible composite materials, usable for air bags, inflatable structures, in general, bags, shoes and similar three-dimensional articles.
[012] In various aspects of the present disclosure, a fabrication system provides precise fit, at desired locations in a tissue-related product, directional control of stiffness, flexibility and elasticity properties.
[013] In various aspects of the present disclosure, fabric-related products combine extremely light weight with extreme strength. BRIEF DESCRIPTION OF THE DRAWINGS
[014] Attached drawings are included to provide a further understanding of the disclosure, in addition, they are incorporated into and constitute a part of this descriptive report, illustrate modalities of disclosure and, together with the description, serve to explain the principles of disclosure, in which:
[015] Figure 1 shows side views of thin projected flexible composite materials adjacent to conventional woven materials according to various embodiments of the present disclosure;
[016] Figure 2 shows a perspective view of a three-dimensional flexible composite article, according to various embodiments of the present disclosure;
[017] Figure 3 shows a sectional view of molding arrangements and tools used to produce three-dimensional articles in accordance with various embodiments of the present disclosure;
[018] Figure 4 shows a sectional view of alternative molding arrangements and preferred tools used to produce preferred articles in accordance with various embodiments of the present disclosure;
[019] Figure 5 shows a sectional view of preferred molding arrangements and tools of Figure 4 according to various embodiments of the present disclosure;
[020] Figure 6 shows a sectional view of an article produced by the preferred molding arrangements and tools of Figure 4 in accordance with various embodiments of the present disclosure;
[021] Figures 7a, 7b and 7c show a schematic diagram, which generally illustrates molding arrangements, tools and alternative preferred steps for the production of preferred flexible composite articles, in accordance with various embodiments of the present disclosure;
[022] Figure 8 shows a perspective view, which diagrammatically illustrates a flexible composite article that contains integrated structural reinforcements for attachment points, through holes and reinforcement strips for increased load carrying capacity, according to various modalities of the present disclosure;
[023] Figure 9 shows a sectional view, diagrammatically illustrating alternative flexible composite materials made with two or more monofilaments, fibers or tows using alternative unidirectional tapes comprising different fibers, according to various embodiments of the present disclosure;
[024] Figure 10 shows a sectional view, which diagrammatically illustrates an alternative flexible composite material made with two or more monofilaments, fibers or tows with the use of alternative unidirectional tapes comprising different fibers, according to various embodiments of the present disclosure ;
[025] Figure 11 shows a perspective view, which diagrammatically illustrates a composite shoe upper, according to various embodiments of the present disclosure;
[026] Figure 12A shows a side view, which diagrammatically illustrates a projected composite shoe upper, according to various embodiments of the present disclosure;
[027] Figure 12B shows a side view, which diagrammatically illustrates a projected composite shoe upper, according to various embodiments of the present disclosure;
[028] Figure 13 shows a partially exploded diagram illustrating a preferred composite construction consistent with the composite shoe upper construction of Figure 11, in accordance with various embodiments of the present disclosure;
[029] Figure 14 shows a diagram that generally illustrates preferred production methods of a modular designed composite shoe upper usable in multiple shoe applications, according to various embodiments of the present disclosure;
[030] Figure 15 shows a diagram that generally illustrates a preferred production method of the composite shoe upper of Figure 11 according to various embodiments of the present disclosure;
[031] Figure 16 shows a diagram that generally illustrates a set of initial manufacturing steps employed in the production of the composite shoe upper of Figure 11, according to various embodiments of the present disclosure;
[032] Figure 17 shows a plan view, diagrammatically illustrating a flat composite component capable of forming a composite shoe upper, according to various embodiments of the present disclosure;
[033] Figure 18 shows a diagram that generally illustrates a set of subsequent manufacturing steps employed in the production of the composite shoe upper of Figure 11, according to various embodiments of the present disclosure;
[034] Figure 19 shows a schematic diagram that generally illustrates a first consolidation and healing methodology employable in the production of the composite shoe upper of Figure 11, according to various modalities of the present disclosure;
[035] Figure 20 shows a schematic diagram that generally illustrates a second consolidation and healing methodology employable in the production of the composite shoe upper of Figure 11, according to various embodiments of the present disclosure;
[036] Figure 21 shows a diagram that generally illustrates an exemplary method of applying a set of finishing components to the composite shoe upper of Figure 11, according to various embodiments of the present disclosure;
[037] Figure 22 shows a diagram that generally illustrates an alternative exemplary method of applying a set of finishing components to the composite shoe upper of Figure 11, according to various embodiments of the present disclosure;
[038] Figure 23 shows a diagram that generally illustrates an alternative exemplary method of assembly of finishing components to the composite shoe upper of Figure 11 according to various embodiments of the present disclosure;
[039] Figure 24 shows an embodiment of a tube formed from rigid Shape Memory Polymer (SMP), according to various embodiments of the present disclosure;
[040] Figure 25 shows an SMP tube further formed into a female mold, in accordance with various embodiments of the present disclosure;
[041] Figure 26 shows the application of fiber tows in a tool rigidly, according to various embodiments of the present disclosure;
[042] Figure 27 shows an embodiment of a superplastic forming type system, in accordance with various embodiments of the present disclosure;
[043] Figure 28 shows an embodiment of a layer-by-layer lamination of unidirectional tape layers and other structural elements onto a male shaped tool, according to various embodiments of the present disclosure; and
[044] Figure 29 shows another embodiment of a layer-by-layer lamination of unidirectional tape layers and other structural elements on a male shaped tool, according to various embodiments of the present disclosure. DETAILED DESCRIPTION OF THE INVENTION
[045] The following description is of various exemplary embodiments only and is not intended to limit the scope, applicability or configuration of the present disclosure in any way. Preferably, the following description is intended to provide a convenient illustration for deploying various modalities including the best mode. As will become more apparent, various changes can be made to the function and arrangement of the elements described in these embodiments without departing from the principles of the present disclosure.
[046] As described in greater detail in the present invention, various embodiments of the present disclosure generally comprise a laminate that includes reinforcing elements therein, wherein such reinforcing elements include at least one unidirectional tape having monofilaments therein, wherein all such monofilaments lie in a predetermined direction within the tape, where such monofilaments have diameters less than 40 microns and where the spacing between individual monofilaments within a monofilament bond-strengthening group are adjacent or are adjacent monofilaments within a span distance in the range between non-contiguous monofilaments of up to fifty times the largest diameter of the monofilament. In various embodiments, the span distance in the range between non-contiguous monofilaments can be up to nine times the largest diameter of the monofilament.
[047] In various embodiments of laminates in accordance with the present disclosure, tows consisting of a bundle of large numbers of monofilaments are extruded, pultrused, or otherwise converted from a plurality of monofilament tows into a ribbon Thin flat unidirectional consisting of a plurality of substantially parallel oriented monofilaments of predetermined thickness, fiber area density, resin matrix coating or embossing specification to satisfy computer structural analysis design specifications or pre-existing specification. Additionally, the reinforcing elements may comprise at least two such unidirectional tapes, each with monofilaments extruded thereon, in all such lying in a predetermined direction within the tape, such monofilaments having diameters less than 40 microns and wherein the spacing between individual monofilaments within a monofilament bond strengthening group are adjacent adjacent monofilaments in adjoining or are within a span distance in the range between non-contiguous monofilaments of up to fifty times the largest diameter of the monofilament. In various embodiments, the span distance in the range between non-contiguous monofilaments can be up to nine times the largest diameter of the monofilament. In various embodiments, unidirectional tapes comprise larger areas without any monofilaments, and wherein such larger areas comprise laminar covers which comprise smaller areas without monofilaments.
[048] Specifications for particular unidirectional tapes used may have different fiber areal densities, resin specifications, spread specifications, layer thickness fiber types and may contain different blends of two or more fibers.
[049] In various embodiments of a laminate according to the present disclosure, the smaller areas comprise user-planned arrangements. In various embodiments, the laminates further comprise an array of water-breathable or waterproof/breathable (W/B) elements that comprise laminar coverings of such smaller areas. Additionally, the laminates may comprise a number of other laminar coverings. Furthermore, a laminate in accordance with the present disclosure may comprise a first of such at least two unidirectional tapes which include monofilaments lying in a different predetermined direction than a second of such at least two unidirectional tapes.
[050] In various embodiments of the present disclosure, a combination of the different predetermined directions of such at least two unidirectional tapes is selected by the user to achieve laminate properties that have planned directional flexibility/rigidity. Furthermore, in various embodiments, a laminate can comprise a flexible composite part in a three-dimensional shape. In various embodiments, a three-dimensionally shaped flexible composite part comprises multiple laminated segments secured along peripheral joints. In various embodiments, the three-dimensionally shaped flexible composite portions comprise at least one laminated segment secured along peripheral joints to at least one unlaminated segment. In various embodiments, such products can comprise multiple laminated segments secured along area joints.
[051] In various embodiments of the present disclosure, a fabric-related product comprises at least one laminated segment secured along area joints to at least one unlaminated segment. Such products may comprise at least one segment laminate attached along area joints to at least one single segment tape. Additionally, such products may comprise at least one laminate segment attached along area joints to at least one monofilament segment. In various embodiments, such products can additionally comprise at least one rigid element. In various embodiments of the present disclosure, at least one unidirectional tape is attached to such a product.
[052] In various embodiments of the present disclosure, a method of producing flexible composite parts in a three-dimensional format comprises the steps of: providing at least one male mold and at least one female mold having compatible configurations; applying at least one first fiber reinforced scrim onto such at least one male mold, said first fiber reinforced scrim comprising two or more layers of unidirectional fibers placed in different orientations; optionally applying at least one second fibre-reinforced scrim onto such at least one male mold and such at least one fibre-reinforced first scrim, wherein said second fibre-reinforced scrim comprises two or more layers of unidirectional fibers placed in different orientations; optionally applying at least one first surface layer onto such at least one male mold, such at least one fibre-reinforced first scrim and such fibre-reinforced second scrim to form a first composite lamination; removing such first composite lamination from such at least one male mold and placing such first composite lamination, in an inverted configuration, within such at least one female mold; optionally using a removable liner by applying at least one removable liner to such at least one male mold; removing such at least one release liner from such at least one male mold and placing such release liner, in an inverted configuration, within such at least one female mold on such first composite lamination; optionally applying at least one second surface layer onto such at least one male mold; applying at least third fiber reinforced scrim onto such at least one male mold and such at least one second surface layer, wherein said third fiber reinforced scrim comprises two or more layers of unidirectional fibers placed in different orientations; optionally applying at least one fourth fiber reinforced scrim onto such at least one male mold, such at least one third fiber reinforced scrim and such at least one second surface layer to form a second composite lamination, wherein said fourth reinforced scrim per fiber comprises two or more layers of unidirectional fibers placed in different orientations; removing such second composite lamination from such at least one male mold and placing such second composite lamination, in an inverted configuration, within such at least one female mold over the first composite lamination; joining along peripheral edges of such first composite lamination and such second composite lamination; and curing such first composite lamination and such second composite lamination to form at least one three-dimensionally shaped article.
[053] In various embodiments of the present disclosure, a method further comprises the optional second fiber reinforced scrim as an additional layer in said first composite lamination.
[054] In various embodiments of the present disclosure, a method further comprises the optional first surface layer as an additional layer in said first composite lamination.
[055] In various embodiments of the present disclosure, a method further comprises the optional second surface layer as an additional layer in said second composite lamination.
[056] In various embodiments of the present disclosure, a method further comprises the optional fourth fiber reinforced scrim as an additional layer in said second composite lamination.
[057] In various embodiments of the present disclosure, a method further comprises the at least one optional removable liner disposed between said first composite lamination and said second composite lamination.
[058] In various embodiments of the present disclosure, a method further comprises the step of forming at least one opening in such at least one three-dimensionally shaped article to aid inflation or other manipulation of such at least one three-dimensionally shaped article. In various embodiments, a method further comprises the step of removing such at least one release liner through such at least one opening. In various embodiments, a method further comprises the step of adding at least one reinforcing structure to such at least one three-dimensionally shaped article.
[059] In various embodiments of the method according to the present disclosure, at least one article in three-dimensional shape is integrated into a shoe. In various embodiments, at least one article in three-dimensional format is integrated into a pouch. In various embodiments, at least one article in three-dimensional shape is gas impermeable. In various embodiments, at least one three-dimensionally shaped article is configured to be gas inflatable. In various embodiments, at least one three-dimensional article is waterproof/breathable (W/B).
[060] In various embodiments of the present disclosure, a method of producing flexible composite parts in a three-dimensional format comprises the steps of: joining two symmetrical flexible composite parts by folding peripheral material from a first part side onto a second part side to form an overlap seam region; and curing such two symmetrical flexible composite parts to form a unitary three-dimensionally shaped flexible composite part having a hollow interior.
[061] According to various modalities of the same, the present system provides each and every resource, element, combination, step and/or innovative method revealed or suggested by this patent application.
[062] Brief glossary of terms and definitions used in the present invention:
[063]Adhesive: A curable resin used to combine composite materials.
[064]Anisotropic: having mechanical and/or physical properties that vary with the direction at a point in a material (ie, non-isotropic).
[065] Area weight: the weight of fiber per unit area, often expressed as grams per square meter (g/m2).
[066]Autoclave: A closed vessel to produce a fluid pressure environment, with or without heat, for a confined object that is undergoing a chemical reaction or other operation.
[067]Stage B: generally defined in the present invention as an intermediate stage in the reaction of some thermosetting resins. Adhesive or crosslinking polymer resins used in prepregs are sometimes pre-reacted to stage, called “prepregs”, to facilitate handling and processing before final curing.
[068]Stage C: final stage in the reaction of certain resins in which the material is relatively insoluble and infusible.
[069]Cure: change the properties of a polymeric resin irreversibly by chemical reaction. Curing can be accomplished by adding curing agents (crosslinking), with or without catalyst and with or without heat. The term healing can refer to a partial process or a complete process.
[070] Decitex (DTEX): unit of linear density of a continuous filament or yarn, equal to 1/10 of a tex or 9/10 of a denier.
[071] Dyneema®: A brand of ultra high molecular weight polyethylene fiber (UHMWPE) supplied by DSM (Heerlen, Netherlands).
[072] Fiber: a general term synonymous with filament.
[073] Filament: the smallest unit a material that contains fiber. Filaments are usually long in length and small in diameter.
[074] Shape: A three-dimensional shape tool for shoes.
[075] Polymer: an organic material composed of linked monomer molecules.
[076] Prepreg: A ready-to-cure tape or foil material where the resin is partially cured to a B stage and supplied to a lamination step before complete curing.
[077] Tow: An untwisted, twisted or interwoven bundle of continuous filaments.
[078] Upper: The portion of a shoe that overlays the upper portion of the foot from the heel to the toe.
[079]UHMWPE: ultra high molecular weight polyethylene. A type of polyolefin made up of extremely long polyethylene chains. Trade names include Spectra® and Dyneema®.
[080] Unidirectional tape: unidirectional tape (or UD tape) which are flexible reinforced tapes (also called sheets) with uniformly or non-uniformly dense arrays of reinforcing fibers in generally parallel alignment and impregnated with an adhesive resin matrix. This resin can be a reactive crosslinking polymer that often contains a catalyst or curing agent and undergoes a non-reversible reaction during processing or a thermoplastic resin that melts and can be reformed by successive heating and cooling. UD tapes are often B-stage and form the basic unit of many composite fabrics.
[081] Viscoelastic material: materials that exhibit both viscous and elastic characteristics when they are subjected to deformation. Such materials can exhibit linear or non-linear rheological response under mechanical loading.
[082] Referring now to Figure 1, various embodiments of a three-dimensional composite article system 100 comprise seamless three-dimensional shaped articles 101 usable for inflatable/air pocket structures, bags, shoes and other three-dimensional articles, based on materials flexible composites. As used in the present invention, seamless refers to items integrally bonded to be structurally seamless. Various modalities of manufacturing processes of the present system are capable of producing flexible parts in three-dimensional format with integrated structures and directional fiber reinforcement. Various articles of three-dimensional composite article system 100 include, but are not limited to, shoes, backpacks/bags, or inflatable parts such as air bags or balls and the like. In traditional three-dimensional shape textile products, flat products cut into complex shapes are sewn or sewn together to produce the three-dimensional shape. In various embodiments of manufacturing processes in accordance with the present disclosure, composite molding methods are combined with innovative precursor materials to form fiber reinforced continuous shaped articles that are flexible and deformable.
[083] Figure 1 further illustrates a side view comparison of an embodiment of a thin designed substantially flexible composite material 103, in accordance with the present disclosure, with a much thicker conventional woven material. In general, the methods described in the present disclosure provide materials substantially thinner than conventional materials.
[084] Figure 2 illustrates, in perspective view, an embodiment of an article in a seamless three-dimensional format 101 according to the present disclosure. In various embodiments, material that is thinner than existing fabrics is possible due to the use of high strength fiber and minimal surface coating. For example, in air bag applications, thin composite materials allow for reduced packaging volumes, as shown in Figure 1.
[085] Current market trends see the expansion of automotive airbag technology in many new applications including aircraft, bus, train/high speed rail systems and for personal head and neck support for sports, motorcycling, motorsports or military applications. This same technology has applications in emergency systems and other commercial buoyancy systems, emergency buoyancy apparel and accessories, avalanche protection, oil and chemical splash control, bladder dams, water reservoirs for outdoor applications, backpacks, tents (ie a small tent or shelter) and general storage systems.
[086]Trends in air bag technology pursue the development of lightweight, thin, high-strength, multi-directionally reinforced pressure-proof envelopes that are resistant to impact and puncture. Controlled deformation and compliance can be used to absorb shock and manage impact impulse. Automotive applications for side curtain, seat and belt protection need to be very light, pack in the smallest possible volume and have the ability to be formed into the most advantageous 3D format for optimal protection development. Often complex 3D shapes need to be strong, exhibit high burst pressure, impact and puncture resistance, and need to inflate to their predetermined shape without bursting or failing any seams/fixtures. They generally need to have a high degree of pressure integrity and impermeability due to the limited volumes of stored pressure inflation media. This is especially critical given the fact that many systems have operational requirements that the bags remain inflated for 7 to 10 minutes after impact and/or placement and for some applications it may be desirable for the bag to remain inflated for much longer. time. An example of this is the helicopter air bag crash system where initial positioning cushions the impact of the helicopter, but in water it is desirable for the bags to remain inflated to provide buoyancy to prevent the helicopter from sinking.
[087] Another similar application where post-inflation pressure and reusability are beneficial is in aircraft air bags for use over water. Air bags are desirable for accident protection on commercial airlines, but weight and storage volume are sought after for these applications. Airlines are already required to carry buoyancy devices onboard for use over emergency water, so if the crash protection function for landing impact can be combined with secondary buoyancy applications, the utility of such systems is enhanced. This technology is equally applicable to commercial aircraft emergency exit glide and also for emergency exit from out of water accident and flotation systems.
[088] In addition to packaging, positioning and inflation requirements, the construction of the air bag using the technology disclosed in the present invention can also enhance and enhance the ability of the air bag to provide protection for life and against injury during the positioning of accident/impact and post-accident protection. The mechanical and high strength properties of the three-dimensionally shaped articles 101 of the present disclosure will have well-controllable placement into predictable shapes. The bag structure can be enhanced for impact absorption and energy dissipation and the impact surface of the bags can be optimized for surface properties such as softness or coefficient of friction to prevent excessive loads, accelerations and rotations on occupant bodies.
[089]Damage tolerance, puncture resistance and extreme resistance to damage propagation by puncture or tear allow the bags to continue to function after local damage without failure or complete rupture.
[090] In various embodiments, a high degree of pressure integrity of three-dimensionally shaped articles 101 in accordance with the present disclosure allows not only prolonged or even permanent inflation, but also the incorporation of practical multi-stage inflation gas systems into the delivery system. air pocket for improved occupant protection, while still meeting storage, packaging, gas storage and volume restrictions. Another benefit of the durability of materials and construction is that air bags in accordance with the present disclosure can be recycled and used multiple times.
[091] In various embodiments of the present system, a layer of scrim is stretched over a male mold and cured into the shape of the mold (see also Figure 15, discussed in the present invention below). A scrim is made of two or more fiber-reinforced layers coated with adhesive, eg unidirectional tapes. More than one layer of scrim can be added, as desired, to improve the dimensional stability and tear strength of the final material. The number of layers, type of adhesive or fiber, type or configuration of surface layer and the initial state of the scrim (uncured or cured) are all variables that can be substituted without changing the basic inventive concept. At least one preferred application of this modality is shoes, in which the slabs can be sewn around a “shape”. Various embodiments of footwear in accordance with the present disclosure are described in a later section on the present invention below. In various embodiments of the present system, additional unidirectional tape layers can be added to limit stretch along specific load paths. In other embodiments of the present system, surface layers may be added to the cured stack around the mold.
[092] In various embodiments, a unidirectional tape layer comprises substantially parallel and finely spread fibers coated by or embedded in a matrix adhesive. The monofilament fibers that make up these unidirectional tape layers are spread so that the monofilaments that make up the fiber are positioned approximately side by side, individually coated with adhesive, or embedded in an adhesive or resin. The positioning can be such that the spacing distance between the monofilaments or the monofilament area weight distribution can be uniform, non-uniform, or such that the monofilament layer incorporates spacing between heavier unidirectional tapes comprising a thickness of several filaments. The positioning can be such that the spacing distance between the monofilaments can be uniform, non-uniform or such that the monofilaments are adjacent or overlapping. In some cases, monofilament tows may incorporate a twisting or braiding of the constituent monofilaments to limit or control spreading. However, the concept of spreading and coating filaments within a fiber that contains many filaments is similar. In various embodiments, the adhesive comprises an elastic polymer. This option gives the unidirectional tape conformance and allows it to be stretched and molded in its unreinforced fiber directions. A layer of unidirectional tape can be individually positioned over the mold for local reinforcement.
[093] Figure 3 shows a sectional view of an embodiment of various molding arrangements and tools usable to produce three-dimensionally shaped articles 101 in accordance with the present disclosure. A method for molding unidirectional tape onto a complex part while maintaining fiber uniformity comprises a step of first creating a scrim in which two layers of flat unidirectional tape are secured together in different orientations such as 0° and 90°, or at any other relative guidance as required by the particular project. The resulting scrim stretches in its orientation directions, but the filaments are stabilized by the reinforcement of the cross layer. This allows the filaments to be positioned and stretched over the mold in a way that maintains filament alignment and minimizes crimped fibers.
[094] One embodiment of a method used to create a three-dimensionally shaped object in accordance with the present disclosure comprises providing a male mold and a female mold that have essentially compatible dimensions. A first 0°/90° scrim can be made from at least one layer of the unidirectional tape. The scrim constructed in this way stretches significantly in the orientation directions and thus can be stretched over the male mold. A second 0°/90° unidirectional tape scrim may be oriented 45° from the first layer and stretched over the male mold and the first scrim. Optionally, a film or surface layer is stretched over the first and second slabs. This first stack can then be removed from the male mold, inverted and placed in the complementary female mold. Optionally, a removable liner, eg Teflon, is stretched over the male mold. The removable liner is then removed from the male mold, inverted and placed in the female mold over the first stack. Then an optional surface layer or film can be stretched over the male mold, this time the first layer in the stack. Next, a third 0°/90° unidirectional tape scrim can be stretched over the male mold. Optionally, a fourth 0°/90° unidirectional tape scrim may be oriented 45° from the first layer and stretched over the male mold and the third scrim. This second stack is then removed from the male mold, inverted and placed in the female mold over the first stack or the optional removable liner. The first stack preferably comprises some excess suspended material that can be folded over the second stack to form an edge joint of the first and second stacks. In various ways, these layers are vacuum packed in the female mold and cured in an autoclave. When the part is cured, the optional removable liner prevents the first and second stacks from joining in places other than bending over the edges. According to such methods, a continuous formed three-dimensional shaped article 101 is created that does not require any additional joining. In various embodiments, the resulting three-dimensional shaped article 101 can be inflated to its final 3D shape by cutting a hole in the layers and filling the portion with air. In various embodiments, the removable liner, when used, can be removed through this hole.
[095]The manufacturing method described above is useful for 3D parts that are symmetrical, such as a sphere, oval, cylinder or cube (see also Figure 2 for an example).
[096] The modality described above implements the union of two symmetrical parts by folding material extended from a lamination above and over another lamination to form a seam that can be cured to be structurally seamless within the composite part formed. After the part is cured, it can be inflated, the second side will reverse and traces of this seam will be located on the centerline of the part. This exemplary method is useful for thin flexible materials where the seam wrinkle becomes negligible once the portion is inflated.
[097] The method disclosed in the present invention is an improvement compared to existing manufacturing processes due to the fact that the resulting part requires only a limited number of secondary processes to complete. For applications where there is limited packaging volume or in cases where weight savings are critical, a part that has minimal seams, which reduces the thickness and/or weight of the part, is beneficial.
[098] Figure 4 illustrates a sectional view of alternative embodiments of molding arrangements and tools usable to produce various articles in three-dimensional format 101 in accordance with the present disclosure. As illustrated in the embodiment of Figure 4, an uncured or formable laminate, such as comprising layers of scrim, can be sandwiched between the layers of flexible diaphragm. The uncured and unformed composite can then be disposed between male and female mold tools for forming and curing.
[099] Figure 5 illustrates a sectional view of a molding modality of molding arrangements and tools and the resulting shaping and curing of the laminated material in a composite part. As illustrated, heat, pressure and/or vacuum can be used in any combination of shaping and curing the laminated structure into a formed composite part. Various methods for shaping and curing include, but are not limited to, autoclave compression, hydroforming, or diaphragm formation, among other methods known to one of ordinary skill in the art.
[0100] Figure 6 illustrates a sectional view of another molding and curing operation in accordance with various embodiments of the present disclosure. In the process illustrated in Figure 6, a previously cured and formed laminated portion, (for example, the portion resulting from the operations disclosed in Figures 4 to 5), is sandwiched between the flexible diaphragm layers and positioned between the male and female tools of the mold. The layered structure, with or without any number of surface layers, is laid on a mold and formed and/or cured using various methods including, but not limited to, autoclave compression, hydroforming or diaphragm formation or other methods that would be known to a person skilled in the art.
[0101] Figures 7a, 7b and 7c show a schematic exploded view of an embodiment of a female mold process according to the present disclosure. In the process disclosed in Figures 7a to c, a part is seated in a mold and an inflatable bladder is inserted into the part to apply pressure within the part to force the material into the shape of the mold as it cures.
[0102] As shown in Figure 7a, a composite part 130a is placed within a female mold 170 and an inflatable bladder 175a is inserted into the composite part 130a to apply pressure to the interior of the part while the part is cured by any one or combination heat, UV, RF and electron beam curing. The elastomeric bladder 175a applies uniform pressure (eg, air or liquid pressure) to the composite part 130a, forcing the part into the shape of the mold.
[0103] Figure 7b illustrates the expanded composite part 130b that shaped the internal shape of the female mold 170. If desired, the elastomeric bladder 175b (now expanded to the shape of the mold) can be cocured to the inner surface of the composite part 130b to form, for example, an internal pressure bladder or inner layer or skin of the article. If this layer of inner bladder material is not needed, the bladder can be deflated and removed from the mold, leaving the expanded and cured portion 130b in place without a layer of cured bladder.
[0104] Figure 7c illustrates an embodiment of a sized composite part 135 removed from the now open mold 170.
[0105] Another exemplary modality, useful for shoe applications, for example, comprises the option of using an inflatable bladder as a 3D training tool, through which composite unidirectional and/or Bd stage, Cd stage composite tapes , or thermoplastic matrix, pre-lined canvas, angle canvas or laminated cut patterns can be layered and mounted thereon. For such embodiments, the inflatable bladder preferably has sufficient structural rigidity to accommodate a layer of materials thereon.
[0106]For purposes of mounting and laminating the shoe upper to an inflatable bladder, at least three ways to solve the bladder stiffness problem can be performed. A first way is to use a multi-component, three-dimensional shaped tool that holds the elastomeric bladder, removable at some point in the manufacturing process to allow the flexible composite part to be removed from the mold and bladder. A second way is to use an elastomeric bladder which can be reinforced with a fabric composite such that it can be pressurized at the point where it is rigid enough to act as a form for application of the constituent components comprising the upper. A third way is to use Shape Memory Polymer (SMP) in conjunction with elastomeric pressure application tools. Such polymers are rigid at low temperature, but are converted to flexible, high-elongation elastomers at temperatures above their transition temperature. Above their transition temperatures, the SMPs can be placed in a heated mold and pressurized to form the tool in its elastomeric phase, accurately doubling the mold shape which, in the case of a shoe molding system, would be the desired shape. to the inside of the shoe.
[0107]As the mold is cooled below the transition temperature of the SMP, the SMP is converted to a rigid solid in the shape of the inner shape dimensions of the shoe upper. In this “rigid” form, the tool can be used as a laminating form tool for the shoe molding process. An example of a structure formed from stiffened SMP is the tube 180 shown in Figure 24. For this embodiment, the SMP was stiffened into tubular form in a mandrel by cooling the SMP below its transition temperature. Figure 25 shows a tube of SMP 181 after the SMP has been heated above its transition temperature, formed into shape within a female mold 182 (only the bottom half of the mold is shown) and then cooled below the temperature of transitioning the SMP, under pressure, to produce the tool rigidly in the shape of the mold cavity 182. Figure 26 shows one embodiment of a process by which fiber tows 183 are applied to the stiffened tool 184.
[0108] In various modalities, such as, for example, in footwear applications, the cured composite upper can be removed from the hardened tool by removing the cured mold assembly slightly above the transition temperature while the SMP is still in its elastomeric shape or removal after the assembly has been removed from the mold by blowing hot air into the interior to soften it for removal. In various other embodiments, the stiffened tool can be left integrated over the composite to keep the composite shape intact and to provide an easily indexable “cartridge” style system for storing, loading and transporting the top of the “chassis” designed in any downstream manufacturing operation. Such downstream operations can include, for example, integration with cosmetic outer layers and top-to-bottom lamination if this step has not already been carried out in the initial molding process (and optionally single-step).
[0109] The tool with the composite shoe laminated over the mold can then be placed in a female mold and the SMP pressurized and heated beyond its transition temperature where it softens and acts as an elastomeric pressure bladder to consolidate and laminate the materials in the upper part of the shoe.
[0110]In alternative embodiments, the film or surface layer can be bonded on one or both sides of the part. These layers can be films (PET, Nylon, ECTFE, urethane, etc.), breathable membranes (Teflon, urethane, etc.), woven or non-woven cloths, leather or other layers. The selection of the surface layer is based on end use requirements such as gas tightness or permeability, water resistance characteristic, abrasion resistance, durability, aesthetics or others.
[0111]In alternative embodiments of the present system, the scrim is precured in a flat shape between removable liners. This material can be sold to manufacturers for subsequent lamination. In various other embodiments of the present system, multiple layers of scrim are stretched over a mold and glued in place by coating each layer with adhesive. In various other embodiments of the present system, an existing adhesive that coats the scrim filaments is thermoplastic and can be melted back together to join the layers. In various other embodiments of the present system, the scrim is precured into a flat shape that has a film or surface layer applied to one or both sides. This extra layer, or layers, can serve a number of purposes, such as being thermoplastic, breathable and/or waterproof. For example, one layer can comprise a breathable waterproof (W/B) membrane. It should be noted that any surface layers incorporated with the scrim in its flat form must not inhibit orientation stretching. Otherwise, the moldability of such a flat product may be reduced.
[0112]In various embodiments of the present system, the scrim may contain multiple layers of unidirectional tape, oriented in 3, 4 or more directions, depending on the structure requirements of the finished part. For example, a shoe may require a scrim with a lamination comprising 90°/45°/-45° orientation of fibers such that there is sufficient stretch in the 0° direction for the scrim to be molded over the toe and such that the main load paths operate below the sides of the shoe. This exemplary multi-layered unidirectional tape scrim may be constructed or supplied in raw form or in versions described in alternative embodiments of this invention, such as precured to a flat form between removable liners or precured to a flat form or roll to roll that has a film or surface layer applied on one or both sides.
[0113] Figure 8 illustrates, in perspective view, a modality of an article in three-dimensional format 101 comprising integrated structural reinforcements for attachment points, through holes and reinforcement strips for carrying capacity of heavy load, according to present revelation. Such integrated structural reinforcements can be made from layers of unidirectional tape or other composite material which are incorporated between or on the surface of the layer of scrims that constitute the part and which are co-cured forming the finished part. By incorporating such structural reinforcements into the part, post-processing bonding steps for attachment points and through hole reinforcement are reduced or eliminated.
[0114] Figure 9 illustrates, in cross section, an embodiment of a flexible composite material 103 comprising two or more monofilaments, fibers or tows using alternative unidirectional tapes comprising different fibers, according to the present disclosure.
[0115] Figure 10 illustrates, in cross section, another embodiment of a flexible composite material 103 comprising two or more monofilaments, fibers or tows using alternative unidirectional tapes, according to the present disclosure.
[0116] Alternative unidirectional tape modalities can be made with two or more monofilaments, fibers or tows, through the use of alternative unidirectional tapes made from different fibers, (can be the same grade with different specifications such as Dyneema SK78 and SK75) or by blending fibers within a single layer of unidirectional tape in a predetermined spacing or interlaced pattern. In various modalities, parameters such as strength, modulus, temperature resistance, cut resistance, tear resistance, impact protection and energy absorption can be designed or optimized, and costs can be minimized, using this concept . Typical design fibers include, but are not limited to, UHMWPE (eg Dyneema®), aramids (eg Kevlar®), liquid crystal polymers (eg Vectran®), carbon fiber of various grades, PBO (eg Zylon®), nylon, polyester (Rayon), PEN, Nomex and other high temperature fireproof fibers, steel fibers or other metals and combinations thereof.
[0117] Composite materials can include the matrix heart or membranes through the use of pigments or dye sublimation. A flame retardant adhesive or polymer can be used or flame retardants can be added to a flammable matrix or membrane to improve flame resistance. Examples of retarding additives include, but are not limited to, Brominated Resin DOW D.E.R. 593, DOW Corning 3 Flame Retardant Resin and polyurethane resin with Antimony Trioxide (such as EMC-85/10A from PDM Neptec Ltd.). Any other flame retardant additives may also be suitable. Flame retardant additives that can be used to improve flame resistance include Fyrol FR-2, Fyrol HF-4, Fyrol PNX, Fyrol 6, and Sa-FRon 7700, although other additives may also be suitable. Flame retardant characteristics and self-extinguishing capabilities can also be added to the fibers through the use of flame retardant fibers such as Nomex or Kevlar, metallic or ceramic yarn filaments, direct addition of flame retardant compounds to the formulation of fiber during the fiber manufacturing process or by coating the fibers with a sizing, polymer or adhesive either incorporates flame retardant compounds mentioned above or others as appropriate. Preferred woven or scrim materials used in the laminate may be pretreated by a supplier to impart flame retardant properties or woven or scrim materials coated and/or infused with flame retardant compounds during the manufacturing process.
[0118] Antimicrobial/antipathogen resistance can be added to composite materials of the present disclosure through the incorporation of one or more of the antimicrobial agents added or coated on polymer resins, or fabrics, and antimicrobial treatments of fibers, monofilaments, filaments or tows used for a composite material. Typical materials include antimicrobial OXiTitan, nanosilver compounds, sodium pyrithione, zinc pyrithione, 2-fluoroethanol, 1-bromo-2-fluoroethane, benzimidazole, fleroxacin, 1,4-butanedisulfonic acid disodium salt, N-oxide 2-(2-pyridyl)isothiourea hydrochloric acid, various quarternary ammonium salts, 2-pyridinethiol-1-oxide, composite zinc pyrithione, composite copper pyrithione, magnesium pyrithione, bispirition, pyrithione, α-Brome Cinnam-Gel ( ABC agent, eg KFO France Co, Ltd.), and mixtures thereof. In various embodiments, fiber forms such as yarns, tows and monofilaments can be treated with nanosilver particles or can have silver coatings applied through electrical or chemical plating, vacuum deposition or coating with a polymer-containing silver compound, adhesive or sizing. Other antimicrobial/antipathogen materials not mentioned in the present invention may also be suitable.
[0119] Various modalities of a process comprising stretching a layer of scrim over a mold and curing it in that position to form a flexible three-dimensional composite part are further demonstrated in the following disclosure related to high-performance composite footwear components .
[0120] Figure 11 illustrates, in perspective view, an embodiment of a composite shoe upper 102 according to the three-dimensional composite article system 100 of the present disclosure. In various embodiments, the composite footwear upper 102 comprises flexible composite materials 103.
[0121] Figure 12A shows a side view, which diagrammatically illustrates an alternative embodiment of the composite shoe upper 102, according to various embodiments of the three-dimensional composite article system 100 of the present disclosure.
[0122] In various embodiments, the composite shoe upper 102 of the present system comprises substantially unitary upper foot support structures using engineered arrangements of substantially flexible composite materials 103. Composite materials can be significantly superior to conventional materials by reason of endurance for weight, which is one of the most important requirements for high performance athletes or sports shoes. Thus, various embodiments described in the present invention are particularly useful in producing such footwear. Potential end-use applications of the modalities described in range from ultra lightweight hiking shoes to extreme performance mountaineering boots to military and industrial boots.
[0123] Footwear, in accordance with the various modalities of the present disclosure, comprising unidirectional tape laminates, gives shoes with high-performance designs a degree of design flexibility for technical engineering to reduce weight characteristics, engineered deployment of directionally customized flexibility, the ability to make the material rigid or malleable in several different directions, deployment of load paths, the ability to make the shoe upper into a one-piece molded “monocoque” structure for manufacturing the upper from multiple sized or cut two- or three-dimensional patterns or preforms cut from laminated and glued multi-directional wide products, and the elimination of sewing and workpiece construction and shoe assembly. This exemplary one-piece laminate design has key performance advantages and the ability to controllably design the stretch, orthopedic, or ankle support by strap or strap.
[0124]According to various modalities, one-piece advantages include, but are not limited to, the following:
[0125]It is not necessary to sew longer load paths, which is especially critical for light shoes;
[0126]the potential elimination of the insole to provide continuous structure from one side of the shoe to the other, removing the requirement that the underside must have a structural portion on the underside of the shoe's transfer loads. This allows for decoupling of the design and integration of the upper and lower parts, which allows the lower part to be more optimized for shock absorption, efficient transfer of muscle power, shock absorption and dampening and also allows for the lower parts. be made with less weight;
[0127]enables sophisticated shoe monocoque design for engineered stretch, breathability, load transmission, biometric integration, and ankle support for protection from injury and the like;
[0128]allows automated shoe manufacturing for cost and labor savings;
[0129] allows for sophisticated shoe upper design and the integrated manufacturing process allows the investment to be amortized over multiple model years and shoe platforms; and
[0130]Design flexibility allows a monocoque to be used on numerous shoes of different styles while still retaining the design benefits that existed in the shoe design and manufacturing process.
[0131] At least for these reasons, the performance of various modalities of composite materials 103 in shoe applications is superior to conventional materials such as leather, synthetic leathers, mesh materials and the like. In addition, the flexible composite materials 103 and their manufacturing processes and manufacturing processes disclosed in the present invention can be tailored specifically for certain design constraints.
[0132] Since the structural “chassis” of the shoe can be decoupled from the outer cosmetic surface design of the shoe, different styles of “chassis” designed for various applications can be combined with the “style”, cosmetic and surface design ( eg texture and surface grip, eg for kicking a soccer ball). Through this method, it is possible to produce shoes that seek and have surface characteristics that are similar, but have very different “chassis fit” or structural arrangement, which can be used to maintain a marked cross-platform style or appearance.
[0133]With the use of trade studies, detailed analysis, and physical experimentation, a range of composite tops is obtained, which provides substantial reductions in component weights without sacrificing strength. The flexible composite materials 103 of the present system can be configured to efficiently accommodate anticipated force loading while providing appropriate levels of mechanical compliance consistent with proper component function. Additionally, various modalities of the present system are compatible between applications; that is, a single upper design can be adapted for multiple end-use applications.
[0134] Referring to the illustration in Figure 12A, various embodiments of composite shoe uppers 102 of the present system comprise projected placements of reinforcement fibers 104 located along critical load paths 106 within the component. Such charge paths 106 can be identified using computer analysis (e.g., three-dimensional finite element analysis and the like) and/or physical testing. Other upper regions are designed to provide wrinkled conformance, for example, to accommodate the biomechanical joint of the user's foot. Referring to the illustration in Figure 12B, the alternative composite shoe uppers 102 of the present system comprise comparatively isotropic arrangements of reinforcing fibers 104. In both exemplary embodiments, the resulting composite structures achieve low structural weight while maintaining appropriate levels of strength, support and durability. Additionally, various fabrication methodologies in accordance with the present disclosure maintain high levels of buildability, as will be described in greater detail in the present invention below.
[0135] Figure 13 shows a partially exploded diagram illustrating an exemplary composition of flexible composite material 103 consistent with the construction of the composite shoe upper 102 of Figure 11. In various embodiments, the composite composition 103 generally comprises stretch cloths and high trim in which the individual layers have been combined in a way to form a single unified composition. In various embodiments, the flexible composite comprises at least one or more structural layers 110 of reinforcing material. Various embodiments of flexible composite compositions 103 comprise multiple layers of material consisting of, for example, continuous surface layers and/or fiber reinforced layers such as scrims and/or engineered arrays of individual fiber tows 114, as shown. The multiple layers 110 are preferably configured to comprise multi-directional cargo handling capability. In various embodiments, the flexible composite compositions additionally comprise one or more non-structural "performance modifier" layers 110. In various embodiments, the composite composition 103 can further comprise a texture and/or color 105 applied to or absorbed into a surface layer. external 110.
[0136] In various embodiments, flexible composites can comprise layers 110 that have substantially identical material composition. In various other embodiments, flexible composites can comprise layers 110 that have various material weights, mechanical properties (conformance) and other properties. In various embodiments, the composite shoe upper 102 comprises one or more layers 110 of unidirectional non-woven (UD) fibers and polymer matrix plies oriented in one or more directions. In various embodiments, a composite lamination can comprise layers 110 that consist of both structural and non-structural materials.
[0137]Various types of reinforcement include, but are not limited to: unidirectional prepreg tapes; unidirectional tows (prepreg or crude fiber single tow reinforcements placed along specific load paths); woven and non-woven stage B composites; C-stage woven and non-woven composites; dry woven cloths or prepreg; one or more layers of spread or unscattered unidirectional lamina of dry fiber or unidirectionally oriented prepreg or layers stitched, adhered or bonded to form broad product cloth: one or more layers of prepreg or dry fiber cloth made from unidirectional spread or prepreg tows not spread or spaced or not spaced in unidirectional guide blade or layers stitched, adhered or bonded to form a broad product cloth; two- or three-dimensional dry or prepreg reinforcement preforms; one-way thermoplastic matrix prepreg tape, unidirectional tow, woven and non-woven composites, or engineered preforms as above with thermoplastic or hybrid thermoplastic; thermoset resin matrix; nanofilament, fiberless nanoparticle reinforcing structural membranes; uniaxially oriented sheet products such as tensioned or stretched UHMWPE in single-layer sheet, multi-layer oriented bonded using a suitable adhesive and then incorporated in a manner generally analogous to unidirectional tapes; or said blade slit tensioned or oriented to form unidirectional tows and dried incorporated or with a suitable adhesive or coating; and combinations thereof.
[0138] Various reinforcement fibers/cloths usable in the present system include, but are not limited to, nylon, polyester, ultra-high molecular weight polyethylene (UHMWPE) (eg, Spectra® and Dyneema®), for and meta- aramids (eg Kevlar®, Nomex®, Technora®, Twaron®), liquid crystal polymer (LCP) (eg Vectran®), polyimide, other synthetic polymers (eg polybenzoxazole (PBO) , polybenzimidazole (PBI), polyimide benzobistiazole (PIBT), poly(p-phenylene benzobistiazole) (PBZT), polylactic acid (PLA), poly(p-phenylene terephthalamide) (PPTA), among others), metal fiber, glass fiber, carbon fiber or combinations thereof.
[0139] Upon reading this descriptive report, those elements of common knowledge in the art will note that, under appropriate circumstances, considering such issues of design preference, user preferences, cost, structural requirements, available materials, technological advances and the like, others now known or later developed reinforcement arrangements of the present invention, such as, for example, use of limbs, rigid or semi-rigid load transfer inserts, application of new coatings and the like may also satisfy.
[0140]As the exemplary components are designed for specific applications, the stacking sequence of constituent material layers 110 may vary between modalities. That is, the particular lamination configuration of a composite laminate, in relation to lamination angles, the blade number at each angle and the exact blade sequence, can vary as desired for a particular application. For example, as discussed in the present invention above, three layers with 0°/90°/45° relative orientations of material layers is only one useful embodiment out of an infinite number of possible orientations. Non-structural material layers 110 can be used when a particular visual or non-structural physical property is required (such as, for example, surface texture, wear resistance, UV protection, abrasion resistance, color, reflectivity and the like) . As a preferred example, a "soft" inner layer 110 is often incorporated within the composite shoe upper 102 as a liner adjacent to the wearer's foot.
[0141]Examples of non-structural materials include, but are not limited to: non-woven cloths (non-structural short fiber random felt); woven cloths; various "soft" lining materials including, for example, non-woven material (non-structural short fiber random felt), knitted and wire-bonded (prepreg) cloths; non-structural membranes (waterproof/breathable, interstitial insulators and the like); non-structural coatings; design appliqués; and various elastomeric materials used for shock absorption, cushioning or for various other purposes.
[0142]The non-structural layers 110 can be arranged in any selected layer position of a composite, as required, for example, by design and performance criteria. In many applications, non-structural layers can be omitted entirely.
[0143]For footwear in general, it may be desirable to have controlled bending built into a shoe, such that some parts of the shoe are soft and pliable. Such flexion can allow optimal freedom and range of motion in a swivel joint such as the ankle area. In many other applications, flexion and compliance may enhance, control or, in the case of protection from injury, restrict or limit the range of motion in one or more directions, simultaneously or separately, to perform an intended purpose or function related to the application. of sport or private footwear.
[0144] One example is an ultra-lightweight basketball shoe designed to exhibit structure designed for optimal load transfer and response to cutting, running, and jumping type movements combined with projected compliance over the entire range of ankle motion normally used by the athlete. , but with built-in ankle support that does not limit mobility or restrict movement in the normal range of motion, but rather acts to support the ankle and limit movement or ranges of motion in which the injury occurs by such rotation or excessive roll up or down due to gripping or twisting the foot.
[0145]The athlete's physical performance can be enhanced due to the shoe's ultra-light weight and freedom of movement in the normal range of motion combined to reduce fatigue. The compliance and engineered load trajectories can provide more efficient conversion of muscle response to athletic performance while providing shock and impact absorption, ankle joint support, and controlled restriction of movement in undesirable ranges of motion such as rotation and twisting along with limiting range of motion in normal directions to prevent injury causing joint hyperextension in injury producing direction modes.
[0146] Systems based on multidirectional oriented unidirectional tapes can exhibit anisotropic material properties that facilitate the design of such engineered compliance systems while simultaneously realizing the benefits of using fibers with a high modulus design and very high strength that de otherwise, they would produce a top that is too stiff or heavy for practical use. Unidirectional tapes can have unidirectional monofilaments all oriented substantially in one direction. In the direction along fiber monofilaments, the unidirectional tape can be very strong and exhibit minimal stretch due to the high Young's Modulus of the monofilaments. In the direction perpendicular to the monofilaments, there may be no reinforcement so that the stretch in that direction is controlled by the properties of the elastomeric matrix. In general, properties can be very compliant or “stretchable” and capable of being subjected to large deformations and recovering from these deformations repeatedly without damage or degradation to the matrix.
[0147] Through the use of two or more unidirectional tapes comprising an elastomeric matrix, with unidirectional reinforcement oriented in the directions in which strength and low stretch are desired and leaving the directions in which conformity is desired without reinforcement, the laminate The resulting one can be made selectively rigid with low stretch along the fiber axis of each unidirectional tape yet compliant in directions where there are no directional reinforcement fibers.
[0148] This selective compliance can be enhanced by the optional addition of a thin elastomer interlayer between each unidirectional tape layer to allow the unidirectional tapes to rotate or articulate within the compliant interlaminar elastomeric layer, which allows more control of compliance outside of steering, facilitates larger deformations and provides the ability to adjust laminate response through the use of various grades of elastomer with different types of viscoelastic response.
[0149] Compliant interlayers can have a single or a combination of the following properties: (1) high restorative energy to impart spring-like properties to the deformed laminate to allow the laminate to store and restore elastic energy; (2) high energy loss and absorbance to absorb and diffuse shocks and impacts; (3) viscoelastic damping to control transient response in transient dynamics; and/or (4) rate sensitivity such that matrix properties stiffen or become more compliant in response to rapidly applied transient loads and shocks.
[0150] Composite properties can be predicted and projected using adaptations of suitably modified aerospace unidirectional composite materials to incorporate non-linear and compliant property matrix material properties and large and non-linear geometric and material deformations.
[0151] Due to the non-linearity in the system, the fiber-dominated properties in geometric axis and especially the matrix-dominated properties of the transverse matrix-dominated direction and the matrix-dominated shear directions must be semi-empirically determined through the constitution of sample laminates and the test to obtain the non-linear stress relationships for the transverse matrix-dominated direction and the shear direction.
[0152]These properties can be used as input parameters for the analysis procedure listed below. Although this procedure is customized for rigid laminates if non-linearity is considered and deformations are within acceptable parameters, strength and strain versus load in any arbitrary direction can be approximated closely.
[0153] Useful constitutive equations of a unidirectional fiber reinforced layer and other mathematical and physical information useful in design processes according to various embodiments of the present disclosure, can be found in several technical books related to the subject of laminated composites. A book on the topic of Finite Element Analysis is “The Finite Element Method” by Thomas J.R. Hughes, and a book on the properties and analysis of composite materials is “Introduction to Composite Materials”, S.W. Tsai and T.H. Hahn.
[0154]As noted above, the physical properties of various modalities of flexible composite materials 103 are generally isotopic (with substantially the same physical properties regardless of direction). Alternatively, to provide specific designed control of force loads (and other performance factors), the physical properties of composite compositions can be anisotropic, with non-uniform mechanical properties and/or other physical properties designed to structurally optimize top part performance composite footwear for a specific application.
[0155] The flexible composite materials 103 mentioned above may include both breathable and non-breathable compositions, or non-porous, porous or air-permeable compositions or material product forms, as required by the application. Additionally, various flexible composite materials 103 may be clear, opaque, colored, printed, or may preferably comprise any combination of the aforementioned visual arrangements. Multiple colored layers and cuts can be used to produce colored patterns.
[0156] In various embodiments, both the reinforcing materials and the unreinforced materials that make up the composite lamination can be encapsulated within a polymer matrix 105. In various embodiments, the composite laminations are consolidated, formed and cured or cast/bonded in the case of thermoplastic or non-crosslinked systems, for example using combinations of heat and pressure.
[0157] Figure 14 shows a diagram that generally illustrates methods of producing modular engineered composite shoe uppers 102 usable in multiple shoe applications. The upper part is produced in a multi-step process comprising design and manufacturing steps. The design phase 202 and the fabrication phase 204 can be computer aided. Manufacturing phase 204 can implement at least one automated manufacturing process.
[0158] In various embodiments, at least one computer-aided design is produced for each unique composite shoe upper 102 configuration. During design phase 202, performance criteria are used to arrive at a composite design. In some cases, a computer model is generated and analyzed to understand the performance of the top under various loads and boundary conditions. Such a computer model, which perfectly utilizes finite element analysis, assists in optimizing the new design by predicting, through computer simulation, the behavior of structures under various field conditions. Once the computer design is optimized, one or more prototypes can be generated for physical testing. The composite shoe upper 102 is concurrently or subsequently analyzed for manufacturing capability, including production cost analysis, material availability, storage stability analysis, and the like. The ability to form, form and wear as a garment if the upper is in a flat configuration and additional 3D forming steps are anticipated. If conventional industrial shoe construction methods were envisioned, design and analysis can also be used to provide sharp forming capability suitable for current industrial manufacturing methods and existing tooling and production equipment. If the prototype's performance is consistent with the performance and fabrication criteria, the superior component design moves to fabrication phase 204. Commercially available analysis packages suitable for such analysis and design include, but are not limited to , NASTRAN, Abaqus, ANSYS and PATRAN.
[0159] Either or both of the design phase 202 and the fabrication phase 204 may include computer-aided design data development usable in automated fabrication of the preferred composite upper portion. An exemplary fabrication sequence is described in a subsequent section of the present disclosure.
[0160]Once manufactured, the composite shoe uppers 102 are in a condition to be integrated into one or more end use products 250 as shown. In various modalities, finished topside components can be stored for future use or immediately advanced to a subsequent manufacturing step or advanced directly for integration into a finished product. Using a single topside design allows the time and cost associated with the initial topside design/analysis to be shared across multiple end products.
[0161] Upon reading this descriptive report, those elements of common knowledge in the art will note that the integration of the upper part into a finished product involves additional manufacturing steps, as generally described in a later section of this disclosure. It is further noted that, depending on the nature of the end-use application, the subsequent integration of the top into a finished product may also involve one or more additional design steps.
[0162] Figure 15 shows a diagram that generally illustrates a modality of a method of production of the composite shoe upper of Figure 11. Figure 15 illustrates a design phase 202 followed by a manufacturing phase 204. The phase of fabrication 204 comprises performing a composite material lamination 206 using at least one mold or similar forming tool 208, as shown. The fabrication step 204 further comprises at least one curing step 210 as shown. Curing step 210 can utilize heat and pressure to harden the polymer matrix through crosslinking polymer chains. In many polymer chemistries, curing can be accomplished by chemical additives, ultraviolet radiation, electron beam, and other processes. Alternatively, the thermoplastic matrix materials can be formed by heat and the multiple layers fused or heat alloyed, ultrasonically or laser welded. Thermoplastic hot melt reactive polyurethane adhesive systems can be bonded using solvent welding techniques, contact adhesives or cross-linking or non-crosslinking adhesives or other suitable methods. If crosslinking adhesive is used, the crosslinking curing methods mentioned above can be used.
[0163] In general, curing techniques include, but are not limited to, pressure and temperature curing; pressure and radiation; and pressure and radiation with heat or combinations thereof.
[0164]In general, heating methods include, but are not limited to, heated hood; radio frequency; electron beam; induction heating; and, an oven, or combinations thereof.
[0165] Figure 16 shows a diagram that generally illustrates an example of a set of initial manufacturing steps employed in the production of the composite shoe upper 102 of Figure 11. In this sequence, the selected flexible composite materials 103 are provided in the form of flat blades 212. Flat blades 212 may comprise any of the structural and non-structural precursor materials described above. Flat sheets 212 can consist of crude fiber compositions or can comprise B-stage (or C-stage) prepreg precursor composites.
[0166] In one or more subsequent steps, additional reinforcing fibers 104 can be added to the blade, for example, with the use of one or more automated fiber lamination processes 214. Additional fiber placements can be designed to anticipate load trajectories, compliance requirements, and the like. The use of fiber placements “in spokes” prevents warping within the composite cloth and, in some applications, provides load paths designed to be stable. In various applications, single-fiber tows or narrow multi-fiber tapes can be sandwiched between layers of material 110 to enhance charge transfer. Alternatively, additional reinforcements can be manually applied. Optional steps include applying additional materials to the blade. Such additional materials may comprise structural or non-structural fiber elements, preformed inserts, pads, graphic appliqués, printing, etc.
[0167] Next, the blade is advanced to a cutting step that uses at least one automated cutting process 216. In this step, a section of the blade, which will eventually form the top component, is cut from the blade, such as through the use of at least one computer-generated pattern developed during the design process. Alternatively, cutting can be performed manually. Alternatively, cutting can be performed at any earlier point in the sequence.
[0168]Various automated cutting methods include, but are not limited to: rotary knife (ie mechanical); ultrasonic; laser; die cut; water gun; and combinations thereof.
[0169] In some applications, it is preferred that the grade markings be applied during the cutting steps to facilitate subsequent manufacturing processes as shown. It is further noted that the manufacturing steps described above can alternatively be carried out in combination with a pre-formed tool, such as a male mold or female mold.
[0170] Figure 17 shows a plan view diagrammatically illustrating a flat composite component 218 capable of forming the composite shoe upper 112, according to an embodiment of the present disclosure. Note that the top-end patterns may comprise additional features not revealed in the diagrammatic illustration of Figure 17.
[0171] Figure 18 shows a diagram that generally illustrates a set of subsequent manufacturing steps employed in the production of composite footwear upper 102 of Figure 11. An appropriate three-dimensional forming tool 208, identified in the present invention as the shape 220 is provided. In the form procedure 222, the flat composite member 218 is dimensioned into the external shaping of the form 220, such as through the use of one or more automated form processes. Alternatively, flexible composite materials can be applied to form 220 manually.
[0172] In various embodiments, the constituent materials can be kept in shape with the use of vacuum-assisted adhesion. Alternatively, temporary adhesives can be used to temporarily position and hold material adjacent to the forming tool. For example, form 220 may be coated with a release material followed by one or more adhesive sizing materials to hold the material adjacent to the form (such materials are composite to wash off or be washed away from the composite material).
[0173] Upon completion of the form 222 procedure, the three-dimensional dimensional flexible composite lamination is moved to the cure step 210 as shown. In several procedures, the curing step 210 is performed with the top positioned over the form 220. In an alternative embodiment, the form 220 is removed prior to curing.
[0174] In an alternative step of the form 222 procedure, additional reinforcing fibers 104 are applied to flexible composite materials 103 during the form 222 procedure (and before curing). In an alternative step of the form procedure 222, additional adhesive polymers 224 are applied to flexible composite materials 103. In such an alternative step, the uncured top component may comprise combinations of pregreg and raw fibers that necessitate the application of additional adhesive polymers. 224, thereby assisting in the subsequent consolidation of the constituent materials into a unified composite component. Various polymeric adhesive resins include thermosets and/or thermoplastics.
[0175]Adhesives can be applied to fibers using one or more of the following non-limiting application techniques: spraying; immersion; thermal films; thermoplastic films; resin injections; and dry powder coating; and combinations thereof.
[0176] In various other modalities of the 222 form procedure, all constituent materials (fibers, membranes, etc.) are applied to the form tool (or alternatively, to the female mold) in an automated fiber placement process. In this process alternatively, single tow fibers and/or blade cloths are applied to the form or mold tool, thereby omitting the flat material fabrication steps disclosed in Figure 16.
[0177] Upon reading this descriptive report, those elements of common knowledge in the art will now observe that, under appropriate circumstances, considering such issues of design preference, manufacturing preferences, cost, structural requirements, available materials, technological advances, etc. , other laminating and shaping arrangements such as, for example, integrating additional preformed patches, spacers, finger pushers, elastomeric inserts, leather or cloth outer surface layers, and similar features with laminating before curing the top component, etc., may be sufficient.
[0178]Therefore, as described above, composite top lamination is performed by one or more of the following non-limiting list of techniques: automated lamination; manual lamination in combination with automated lamination; fully manual lamination for preset or low volume work; flat lamination (as generally disclosed and described in Figure 16); partial preform lamination; lamination in male form (placement of single tow and/or cloth with trim); lamination inside a female tool (fiber placement with single tow and/or draped cloth); and automated tool laminations (through which all fiber placement takes place in the form or mold tool); and, combinations thereof.
[0179] Figure 19 shows a schematic diagram that generally illustrates a first consolidation and healing methodology employable in the production of the composite shoe upper of Figure 11. In this example, a rigid female tool 252 is used to deploy a process of female mold curing. In this fabrication technique, internal (ie, outward) pressure is used for consolidation.
[0180] In the exemplary female mold curing processes, the composite lamination is located within the female tool cavity 252 between the internal surfaces of the female mold and a hydroform type chuck, inflatable diaphragm, or similar elastomeric bladder. A pressurized fluid is preferably used to inflate the elastomeric tool and press the composite lamination against the inner surfaces of the female tool 252. In most cases, the fluid and/or tool is heated to facilitate curing of the adhesive polymer matrix. Once the cure cycle is complete, the inflatable elastomeric tool is deflated and the cured or stage B top component is removed from the 252 female tool. It is noted that this exemplary technique, as diagrammatically revealed in Figure 19 (and , in other embodiments, as illustrated in Figures 7a to ac), is well suited for producing composite tops that require external detailing or finished external appearance.
[0181] Alternatively, an inflatable form 220 is used in combination with a female tool 252. In that case, the form is sufficiently rigid to allow lamination during the form 222 procedure (eg, see Figure 18), while preferably holding the ability to deform sufficiently to be removable from the finished top component.
[0182] Figure 20 shows a schematic diagram that generally illustrates a second consolidation and cure methodology employable in the production of the composite shoe upper of Figure 11. Figure 20 generally reveals a male mold process that uses, by For example, the substantially rigid male form 220. In this exemplary manufacturing technique, external pressure is used to consolidate the composite materials. This technique is useful for providing smooth internal surfaces within the top component.
[0183] Such male tool processes may include implantation of vacuum bags, elastomeric outer bladders, mold boxes (with the use of pressure or thermal expansion for consolidation pressure) and the like. The system can support curing within a vacuum and/or atmospheric autoclave. Various embodiments of the rigid male form 220 comprise an arrangement of vacuum ports to provide vacuum-assisted lamination (e.g., to contain the constituent materials in the form during lamination and forming procedures). This technique is also adaptable for using super-plastic forming techniques and other similar vacuum or pressure forming techniques to form flat sheets of unidirectional laminates into large B-stage or C-stage uncured thermoplastic matrix products or flat preforms. engineered or heat-formable into a three-dimensional shape for use directly in a shoe or as a three-dimensional preform for application over the shoe forming tool, mold, or mandrel.
[0184] One modality of a superplastic forming type system is shown in Figure 27. In Figure 27, a top 185 comprises plastically formed flat sheets of wide multidirectional products with a thermoplastic matrix cut into patterned panels formed in 3D and laminated together, such as in a single-step operation. Figures 28 and 29 demonstrate embodiments of a layer-by-layer lamination of unidirectional tape layers and other structural elements onto a male shape tool, including the incorporation of integrated looped strip elements that integrate loop loads into the part housing. higher. This loop-strap element provides a strong loop that introduces loop load distribution evenly and reliably into the light, thin upper, and allows for optimal design of load paths within the shoe to channel and direct loads to optimize transmission of user load for individual intended purpose of application and individual shoe design.
[0185] In various embodiments, as shown in Figures 28 and 29, the upper is continuous around the bottom of the upper, and the load paths on both sides of the shoe are integrated into the upper casing. This unique load path continuity capability potentially allows for structural decoupling of the top from the bottom, eliminating the need for the bottom to carry primary structural loads. This load trajectory continuity capability potentially enables optimization of shock absorption and load distribution while allowing for more effective load trajectory design optimization and overhead load management. This also allows viscoelastic layers to be incorporated between the high strength and low stretch structural connections, and allows the upper shoe structure to manage shock, cushion impact upon running or other activities, and to potentially stiffen the shoe structure under acute transient impact events such as the kick of a ball through which there are brief transient ball/shoe impact events. The ability to stiffen the shoe under kick impacts potentially improves the kicker's kicking performance while still allowing the shoe to be ideally compliant for cutting and running directions and while maintaining comfort. This brief stiffening of the shoe structure during transient kick impact loads enhances and potentially optimizes the load transmission from the kicker foot to the ball to transform more of the kicker muscle effort into imparting more thrust and transmitting more power to the ball when kicked to allow the kicker to kick the ball faster and farther. The shoe's stiffening also makes it more stable so kicking accuracy is potentially improved over a shoe that needs to wear looser to maintain compliance and required comfort levels.
[0186] In the male tool curing procedures of Figure 20 or the female tool curing procedures of Figure 9, the mold tool modalities may use elastomeric mold boxes/split molds comprising external and/or external mold surfaces elastomeric. In each procedure, mold tools can additionally utilize injection molding to produce internal and/or external component features, as diagrammatically indicated in Figure 21.
[0187] Injection molding can be used to infuse or inject resin into dry fiber or partially impregnated materials or preforms or alternatively to create an injectable thermoplastic or thermosetting hybrid and resin to form an alloyed hybrid resin or adhesive system.
[0188] Resin injection can also be used to reproduce external and/or internal transfer component characteristics, textures or surface finishes built into the internal and external mold surfaces, such as embossed patterns, shapes, and to incorporate into the surface of tools or surface layers, as diagrammatically indicated in Figure 21.
[0189] Inner and outer mold surfaces may also incorporate molded, etched or machined patterns, textures, negative or positive prints, or pockets to provide patterns, shapes, geometric features, embossed simulated leather or cloth textures, grooves, perforations, graphics, simulated stitching or seams, graphics, logos, glossy or matte surface finishes. The surface can be formed using various methods such as spraying, immersed or brushed surface resin, directly applied to the patterned mold surface, a compliant surface film or formed by heat or vacuum on the tool surface, or the pattern of mold can be transferred directly from the mold surface and impressionable surface finish applied to the top specifically designed to accept and transfer patterns in the mold.
[0190]Insert elements such as heel supports, stiffeners and insoles can be directly molded during the single operation process using preformed thermoplastics, thermoplastic matrix carbon fiber or prefabricated or prefabricated details. -Formed reinforced by fiberglass or can be co-cured on top using a compatible thermoset matrix.
[0191] Features such as finger pushers, heel supports, appliqués, items or blocks for kicking balls or abrasion guards, can be placed in pockets or print forming the negative of the component to locate and attach the component to the top during the top molding step as a single operation process or secondary process. Features, such as finger pushers, can be fully or partially cured elastomers or molded thermoplastics. Bonding can be through the methods discussed in the present invention or through coking in the case of the partially cured elastomer. Topside adhesive matrix or surface coating can alternatively be used to bond the detail components if appropriate.
[0192]These surface details can also be bonded after the molding step using similar techniques used for actual shoe production.
[0193] Figure 21 shows a diagram that generally illustrates a method of applying a set of finishing components to the composite shoe upper 102 of Figure 11. Figure 21 generally reveals what can be described as an inclusive molding of “ single operation”. In this procedure, external features (e.g., sole components 254, molded supports, etc.) are applied within a closed mold tool during curing step 210. Such inclusive "one-shot" molding may utilize molding processes by injection modified as shown. In an exemplary arrangement of the system, female tool 252 is modified to comprise one or more polymer injection molding components 256, as shown. In various embodiments, one or more elastomeric polymers are injected into the mold tool to form, for example, a resilient sole component. The curing process forms a permanent connection between the composite shoe upper 102 and the injected component. Injection time and polymer chemistries can be chosen to maximize compatibility with the cure cycle of the composite materials that make up the top component. Various elastomeric materials are selected based on required mechanical performance, molding process, cost and the like. Various molded materials include, but are not limited to, ethylene vinyl acetate (EVA), foamed polyurethanes, flexible polyvinyl chlorides, viscoelastomeric materials, and the like.
[0194] Figure 22 shows a diagram that generally illustrates one modality of a method of applying a set of finishing components to the composite shoe upper of Figure 11. In this exemplary method, one or more elastomeric materials 251 are introduced in an open multipart molding that contains precured or uncured 102 composite shoe uppers. The mold parts of the multi-part mold are then assembled to form a substantially enveloped negative print cavity that has an internal shape that matches the features of the sole component. The exemplified process can form a permanent connection between the composite shoe upper 102 and the molded component.
[0195] Figure 23 shows a diagram that generally illustrates an alternative method of applying a set of finishing components to the composite shoe upper of Figure 11. In this alternative method, a preformed sole is bonded or otherwise way, permanently attached to the cured composite shoe upper 102.
[0196]Various three-dimensional one-piece parts according to the present disclosure are relatively inexpensive because of the low specific cost per unit performance of high performance fiber uses, low cost low cost conversion, readily available high denier tow for tapes light and thin unidirectional and the potential ability to automate the fabrication and production of the upper part, the use of a “Single Operation Molding System” to produce the finished upper part. The cost can also be reduced if the top is connected to the bottom as a single operation process. Improved shape fidelity (mainly due to precision tolerance of 3D molding) allows for efficient downstream production and automation of the rest of the manufacturing steps and understands better pressure integrity, understands better integration of structural details (tie, attachment points , etc.), does not include seams for failure or leakage and includes uniform tension, among other advantages.
[0197] It will be evident to those skilled in the art that various modifications and variations may be made to the present disclosure without departing from the spirit or scope of the disclosure. Accordingly, the present disclosure is intended to cover the modifications and variations provided in this disclosure that fall within the scope of the appended claims and their equivalents.
[0198] Likewise, several features and advantages were presented in the preceding description, including several alternatives along with the details of the structure and function of the devices and/or methods. The disclosure is for illustration only and as such is not intended to be comprehensive. It will be evident to those skilled in the art that various modifications can be made, especially in matters of structure, materials, elements, components, shape, size and arrangement of parts including combinations within the principles of disclosure, to all content indicated by the broad meaning of the terms in which the appended claims are expressed. To the extent that these various modifications do not depart from the spirit and scope of the appended claims, they are intended to be covered therein.

权利要求:
Claims (15)
[0001]
1. Method of production of flexible composite parts in three-dimensional format, in which said method is CHARACTERIZED by the fact that it comprises the steps of: a. providing at least one male mold and at least one female mold having compatible configurations; B. applying a first composite lamination by applying at least one fiber reinforced scrim, wherein said fiber reinforced scrim comprises two or more layers of unidirectional fibers placed in different configurations; ç. transfer the first composite lamination from the male mold to conform with the female mold; d. placing at least one release liner within the female mold over said first composite shaped lamination; and. applying a second composite lamination of at least one fiber reinforced scrim, wherein said fiber reinforced scrim comprises two or more layers of unidirectional fibers placed in different configurations; f. transferring said second composite lamination from the male mold to the female mold over said first composite lamination; g. peripherally bending the first composite lamination so as to overlap the periphery of the transferred second composite lamination; and h. cure the first and second laminations to form a three-dimensionally shaped part.
[0002]
2. Method according to claim 1, CHARACTERIZED by the fact that the first and/or second composite lamination comprises at least two fiber reinforced scrims.
[0003]
3. Method according to claim 2, CHARACTERIZED by the fact that a compatible interlayer is present between at least two fiber reinforced scrims in the first and/or second composite lamination.
[0004]
4. Method, according to the preceding claims, CHARACTERIZED by the fact that the first and/or second composite lamination further comprise a surface layer.
[0005]
5. Method, according to any one of the preceding claims, CHARACTERIZED by the fact that it further comprises the step of adding a layer of a waterproof breathable membrane (W/B).
[0006]
6. Method according to claim 1, CHARACTERIZED by the fact that it further comprises the step of forming at least one opening in the part in three-dimensional format.
[0007]
7. The method of claim 2, characterized in that it further comprises the step of removing such an optional removable liner through at least one opening.
[0008]
8. Method, according to any one of the preceding claims, CHARACTERIZED by the fact that it further comprises the step of adding at least one reinforcement unit and/or fibers along the load paths.
[0009]
9. Method, according to any one of the preceding claims, CHARACTERIZED by the fact that it further comprises a step of integrating structural reinforcements for attachment points, through holes and reinforcement strips to increase the load-carrying capacity.
[0010]
10. Method according to claim 1, CHARACTERIZED by the fact that it further comprises a step of integrating the three-dimensional part of step h in footwear/shoes.
[0011]
11. Method according to claim 1, CHARACTERIZED by the fact that it further comprises a step of integrating the three-dimensional part of step h into a backpack bag.
[0012]
12. Method according to claim 1, CHARACTERIZED by the fact that it further comprises a step of integrating the three-dimensional part of step h into inflatable parts including air pockets.
[0013]
13. Method, according to any one of the preceding claims, CHARACTERIZED by the fact that the male mold comprises an inflatable bladder configurable by pressurization internal to an inflated bladder having said three-dimensional shape.
[0014]
14. Method according to any one of the preceding claims, CHARACTERIZED by the fact that the fiber reinforced scrim comprises UHMWPE.
[0015]
15. Part in three-dimensional format CHARACTERIZED by the fact that it is produced by the method, as defined in any of the preceding claims.

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同族专利:

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公开号 | 公开日

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CN105102213A|2015-11-25|

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AU2013342132B2|2017-07-20|

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KR102158890B1|2020-09-23|

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JP6525883B2|2019-06-05|

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BR112015010690A2|2017-07-11|

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US20140134378A1|2014-05-15|

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WO2014074966A3|2014-07-03|

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US20210229374A1|2021-07-29|

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EP2917031A2|2015-09-16|

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US9993978B2|2018-06-12|

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AU2013342132A1|2015-07-02|

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US20180361683A1|2018-12-20|

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KR20150082597A|2015-07-15|

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CN105102213B|2018-08-10|

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EP2917031A4|2016-12-07|

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WO2014074966A2|2014-05-15|

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US20160001472A1|2016-01-07|

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JP2016503360A|2016-02-04|

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CA2891264A1|2014-05-15|

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US9114570B2|2015-08-25|

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CA2891264C|2021-01-05|

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法律状态:
2017-11-28| B25A| Requested transfer of rights approved|Owner name: DSM IP ASSETS B.V. (NL) |

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2018-03-06| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-13| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|

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2018-03-20| B06I| Publication of requirement cancelled [chapter 6.9 patent gazette]|Free format text: ANULADA A PUBLICACAO CODIGO 6.6.1 NA RPI NO 2462 DE 13/03/2018 POR TER SIDO INDEVIDA. |

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2019-12-03| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-03-02| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-05-11| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 09/11/2013, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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US201261724375P| true| 2012-11-09|2012-11-09|

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US61/724,375|2012-11-09|

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US201361780312P| true| 2013-03-13|2013-03-13|

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US61/780,312|2013-03-13|

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US201361800452P| true| 2013-03-15|2013-03-15|

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US61/800,452|2013-03-15|

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PCT/US2013/069364|WO2014074966A2|2012-11-09|2013-11-09|Systems and method for producing three-dimensional articles from flexible composite materials|

---